Synthetic approach to aphidicolan and stemodan basic skeletons using a "Tandem Principle" [2+2+2] and [4+2] cycloaddition reactions

DOI: 10.1016/0040-4039(94)85068-2

Source and publish data:

Tetrahedron Letters p. 417 - 420 (1994)

Update date:2022-08-02

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Authors:

Stammler, Robert

Halvorsen, Karine

Gotteland, Jean-Pierre

Malacria, Max

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Article abstract of DOI:10.1016/0040-4039(94)85068-2

A strategy based upon the "Tandem Principle" : coupling of the cobalt catalyzed [2+2+2] cycloaddition and an intramolecular [4+2] Diels-Alder reaction allowed the formation of the stemodan skeleton in 11 high yield steps starting from 4-ethoxycarbonyl cyclohexanone.

Full text of DOI:10.1016/0040-4039(94)85068-2

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