Asymmetric synthesis of bicyclo[4.3.0]nonan-8-ones by intramolecular Pauson-Khand reaction

DOI: 10.1016/S0957-4166(00)86192-3

Source and publish data:

Tetrahedron Asymmetry p. 307 - 310 (1994)

Update date:2022-08-05

Topics: Asymmetric synthesis Intramolecular Pauson-Khand Reaction Experimental

Authors:

Castro Castro

Moyano Moyano

Pericas Pericas

Riera Riera

Greene Greene

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Article abstract of DOI:10.1016/S0957-4166(00)86192-3

The intramolecular Pauson-Khand reaction of (E)-1-alkoxy-1-octen-7-ynes derived from (1S,2R)-2-phenylcyclohexanol is described. 7-Alkoxybicyclo[4.3.0]non-1(9)-en-8-ones are obtained in yields up to 65% and with diastereoselectivities higher than 10:1. The

Full text of DOI:10.1016/S0957-4166(00)86192-3

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