Tetrahedron Asymmetry p. 307 - 310 (1994)
Update date:2022-08-05
Topics: Asymmetric synthesis Intramolecular Pauson-Khand Reaction Experimental
Castro
Moyano
Pericas
Riera
Greene
The intramolecular Pauson-Khand reaction of (E)-1-alkoxy-1-octen-7-ynes derived from (1S,2R)-2-phenylcyclohexanol is described. 7-Alkoxybicyclo[4.3.0]non-1(9)-en-8-ones are obtained in yields up to 65% and with diastereoselectivities higher than 10:1. The
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