Optically Pure Haloselenuranes. First Synthesis and Nucleophilic Substitutions

DOI: 10.1021/jo00091a008

Source and publish data:

Journal of Organic Chemistry p. 3262 - 3264 (1994)

Update date:2022-08-05

Topics:

Authors:

Takahashi, Tamiko

Kurose, Noriyuki

Kawanami, Saburo

Arai, Yoshitsugu

Koizumi, Toru

Shiro, Motoo

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Article abstract of DOI:10.1021/jo00091a008

The first synthesis of optically pure haloselenuranes 1 has been accomplished by utilizing the 2-exo-hydroxy-10-bornyl group as a chiral ligand.Complete retention of the configuration has been observed in interconversion reactions between haloselenuranes

Full text of DOI:10.1021/jo00091a008

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