Optically Pure Haloselenuranes. First Synthesis and Nucleophilic Substitutions

DOI: 10.1021/jo00091a008

Source and publish data:

Journal of Organic Chemistry p. 3262 - 3264 (1994)

Update date:2022-08-05

Topics:

Authors:

Takahashi, Tamiko

Kurose, Noriyuki

Kawanami, Saburo

Arai, Yoshitsugu

Koizumi, Toru

Shiro, Motoo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00091a008

The first synthesis of optically pure haloselenuranes 1 has been accomplished by utilizing the 2-exo-hydroxy-10-bornyl group as a chiral ligand.Complete retention of the configuration has been observed in interconversion reactions between haloselenuranes

Full text of DOI:10.1021/jo00091a008

Products guided by the article

Product name:(1S,3R,5R,7R)-3-Fluoro-10,10-dimethyl-3-phenyl-4-oxa-3λ⁴-selena-tricyclo[5.2.1.0^1,5]decane

Cas No:156832-22-3

R&D Labs maybe for 156832-22-3

Zhenjiang Haitong Chemical Industry Co., Ltd.

Contact:+86 (511) 8448-0369

Address:Baoyan Town, Dantu District, Zhenjiang City, Jiangsu, China
Shanghai PotentPharm Science and Technology Co.,Ltd

Contact:86-021-51969655

Address:Unit B, Building 18, No.300, Chuantu Rd,Pudong District, Shanghai 201202, China
Phytomarker Ltd.(expird)

Contact:+86-22-26358246

Address:601-4-20, Fujiayuan, Tiantai Road, Hebei District, Tianjin, China
Suzhou Ryan Pharmachem Technology Co.,Ltd

Contact:+86-0512-68780025

Address:B-301,No.2 Taishan Road,Suzhou New District,Jiangsu,P.R. China
Wuhan Kemi-Works Chemical Co., Ltd

website:http://www.kemiworks.com

Contact:86-27-85736489

Address:Rm. 1503, No. 164, Jianghan North Rd., Wuhan, 430022 China

Relevant to this article

Three-component coupling approach for the synthesis of diverse heterocycles utilizing reactive nitrilium trapping

Doi:10.1021/ol500328t
(2014)
Synthesis and biological activity of new cephem compounds with a 3-(2-butenyl)- and a 3-(1,3-butadienyl)group at their 3-position

Doi:10.7164/antibiotics.49.1179
(1996)
Doi:10.1016/0040-6031(91)80279-R
(1991)
Terpenoid Chirons: Preparation and Transformations of 2-Hydroxy-1,1,4a(R),6-Tetramethyl-Trans-Δ^5,6-Octalin

Doi:10.1016/S0040-4039(00)73036-X
(1994)
PPh₃-catalyzed ring-expansion reactions of sulfamate-derived cyclic imines with acetylenedicarboxylates

Doi:10.1002/asia.201301082
(2014)
Synthesis of glucosylceramide analogues. Imino-linked 5a-carbaglycosylceramides, potent and specific glucocerebrosidase inhibitors

Doi:10.1039/c39940001317
(1994)

Article Doi