Journal of Organometallic Chemistry p. 39 - 42 (1994)
Update date:2022-08-03
Topics:
Mitchell, T. N.
Kowall, B.
1,2-Bis(chloromercuri)alkenes, 1-trimethylsilyl-2-chloromercuri-alkenes and 1-trimethylsilyl-2-organomercurialkenes can be readily made by transmetallation of the corresponding trimethyltin compounds with HgCl2 and RHgCl; their structures have been confirmed by multinuclear NMR data.The new compounds are expected to have a large synthetic potential involving lithium/mercury exchange, and subsequent reaction with electrophilic reagents.Key words: Mercury; Nuclear magnetic resonance; Tin; Silicon
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