Synthesis of optically active 4-substituted 2-aminobutyrolactones and homoserines by combined aldol/photocyclization reactions of chromium aminocarbene complexes

DOI: 10.1021/ja00101a014

Source and publish data:

Journal of the American Chemical Society p. 9927 - 9934 (1994)

Update date:2022-08-04

Topics: Synthesis Optically active Aldol Reaction Photocyclization

Authors:

Schmeck, Carsten

Hegedus, Louis S.

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Article abstract of DOI:10.1021/ja00101a014

Aldol reactions of optically active chromium aminocarbene complexes proceeded with moderate to high diasteroselectivity. Photolysis of the aldol product gave optically active 4-substituted 2-aminobutyrolactones which could be hydrolyzed to γ-hydroxy-α-ami

Full text of DOI:10.1021/ja00101a014

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