Formamide as a superior nitrogen nucleophiIe in palladium(II) mediated synthesis of imidazolidines

DOI: 10.1016/0040-4039(94)88488-9

Source and publish data:

Tetrahedron Letters p. 9281 - 9284 (1994)

Update date:2022-08-05

Topics:

Authors:

Van Benthem

Hiemstra

Longarela

Speckamp

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Article abstract of DOI:10.1016/0040-4039(94)88488-9

Formamides emerge as superior nitrogen nucleophiles in palladium(II) catalyzed oxidative 5-exo cyclizations of formaldehyde aminals derived from N-Boc protected allylic amines. The product imidazoridines are readily transformed into protected vicinal diam

Full text of DOI:10.1016/0040-4039(94)88488-9

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