Journal of Organic Chemistry p. 4549 - 4558 (1995)
Update date:2022-07-30
Topics:
Hitotsuyanagi, Yukio
Nishimura, Kunihiko
Ikuta, Hiroshi
Takeya, Koichi
Itokawa, Hideji
An antitumor alkaloid, sinococuline 81), and its C-6 and/or C-7 epimeric analogs 3-5 have been synthesized from sinomenine (2).The carbonyl transposition from 9 to 8 using selenoxide chemistry proceeded in an efficient manner.Successive C-6 hydroxylation
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