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Linear Face-sharing Trioctahedral 3- by Spontaneous thf Loss from -: Structure, Bonding and Magnetic Properties

DOI: 10.1039/c39950001265

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1265 - 1266 (1995)

Update date:2022-07-29

Topics:

Authors:

Fettinger, James C.

Mattamana, Sundeep P.

O'Connor, Charles J.

Poli, Rinaldo

Salem, Ghadi

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Article abstract of DOI:10.1039/c39950001265

Complexes 3- (X = I, Br) assemble by spontaneous thf loss in noncoordinating solvents from - and exhibit a linear free-shared trioctahedral structure with, at the same time, delocalized metal-metal bonding and local moment antiferromagnetic exchange interactions.

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Full text of DOI:10.1039/c39950001265

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