Light- and Heat-Induced Geometric Isomerization of Chloro(hydrido)iridium(III) Complex Containing a (2-Phosphinoethyl)silyl Chelate Ligand

DOI: 10.1246/cl.1995.1005

Source and publish data:

Chemistry Letters p. 1005 - 1006 (1995)

Update date:2022-07-29

Topics:

Authors:

Okazaki, Masaaki

Kawano, Yasuro

Tobita, Hiromi

Inomata, Shinji

Ogino, Hiroshi

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Article abstract of DOI:10.1246/cl.1995.1005

Photolysis of chloro(hydrido)(silyl)iridium complex (PMe3)2> (1) caused the geometric isomerization to 2 which reached to a photostationary state with the ratio of 1:2=29:71.Both 1 and 2 take mer configuration, but 1 has a hydr

Full text of DOI:10.1246/cl.1995.1005

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