Light- and Heat-Induced Geometric Isomerization of Chloro(hydrido)iridium(III) Complex Containing a (2-Phosphinoethyl)silyl Chelate Ligand

Article abstract of DOI:10.1246/cl.1995.1005

Photolysis of chloro(hydrido)(silyl)iridium complex (PMe3)2> (1) caused the geometric isomerization to 2 which reached to a photostationary state with the ratio of 1:2=29:71.Both 1 and 2 take mer configuration, but 1 has a hydr