Rearrangements of O-protected glycosylenamines. A new and efficient route for the synthesis of O-protected 4-aminoaldoses

Article abstract of DOI:10.1016/0040-4039(95)01737-3

O-Protected 4-deoxy-4-diethoxycarbonylvinylaminoaldoses with D-galacto, L-arabino and L-lyxo configurations (3) are prepared by a nucleophilic rearrangement of easily available glycosylamine derivatives.