Tetrahedron p. 1413 - 1416 (1982)
Update date:2022-08-05
Topics:
Jullien, J.
Pechine, J. M.
Perez, F.
Piade, J. J.
Thermolysis at 800 deg C of a series of β-keto-trimethylsilyl-enol-ethers allows the elimination of a trimethylsilanol molecule through a 1,5 rearrangement.The reduction products are furanic derivatives, which are obtained in often good yields through an allenic intermediate, which has been isolated.
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