Tetrahedron p. 2603 - 2628 (1996)
Update date:2022-07-29
Topics:
Louwrier, Saskia
Ostendorf, Martin
Boom, Arnoud
Hiemstra, Henk
Speckamp, W. Nico
Highly stereoselective N-acyliminium ion coupling reactions of β-ketoester derived silyl enol ethers with enantiopure lactams derived from (S)-malic acid are reported. This reaction type is applied in the synthesis of the enantiopure C-2 substituted lactam 27, a plausible intermediate in a projected synthesis of ptilomycalin A.
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(2001)
