Synthesis of asymmetrical aryl-tin compounds by cleavage of alkyl-tin bonds with sodium metal in liquid ammonia followed by SRN1 reactions with chloroarenes

DOI: 10.1016/0022-328X(95)05800-5

Source and publish data:

Journal of Organometallic Chemistry p. 1 - 8 (1996)

Update date:2022-07-30

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Authors:

Yammal, Carlos C.

Podesta, Julio C.

Rossi, Roberto A.

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Article abstract of DOI:10.1016/0022-328X(95)05800-5

One methyl-tin bond was selectively cleaved from aryltrimethyltin compounds by sodium metal in liquid ammonia. The triorganylstannyl anions thus obtained are arylated by chloroarenes by means of photostimulated S_RN1 reactions. Such reactions ca

Full text of DOI:10.1016/0022-328X(95)05800-5

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