Enantioselective addition of Grignard reagents to a 2-thiazolyl nitrone

DOI: 10.1016/0957-4166(96)00060-2

Source and publish data:

Tetrahedron Asymmetry p. 667 - 670 (1996)

Update date:2022-08-02

Topics: Isolation and Purification Workup Reaction Setup Analysis Enantioselective Addition

Authors:

Merchan, Francisco L.

Merino, Pedro

Rojo, Isabel

Tejero, Tomas

Dondoni, Alessandro

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Article abstract of DOI:10.1016/0957-4166(96)00060-2

The addition of organomagnesium compounds to the N-benzyl 2-thiazolyl nitrone 1 in the presence of various chiral additives and Lewis acids leads to hydroxylamines 2 in moderate to good enantiomeric excess (up to 74%); the reductive dehydroxylation of the

Full text of DOI:10.1016/0957-4166(96)00060-2

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