Chemistry Letters p. 301 - 302 (1999)
Update date:2022-08-03
Topics:
Kim, Jong Chul
Ohga, Yasushi
Asano, Tsutomu
Pressure dependence of the rate of thermal geometrical isomerization of 3,3′-diethyloxadicarbocyanine iodide (DODCI) was studied in ethanol and in a highly viscous hydroxylic solvent, 2-methyl-2,4-pentanediol. The kinetic effects of pressure in the two solvents are qualitatively different and the results strongly suggest that the stochastic analysis of the kinetic results in 1-alkanols reported earlier needs to be renounced.
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