Total synthesis of (-)-solavetivone using enantioselective copper-catalysed conjugate addition of Me3Al to a cyclohexa-2,5-dienone intermediate

DOI: 10.1039/CC9960001655

Source and publish data:

Chemical Communications p. 1655 - 1656 (1996)

Update date:2022-08-04

Topics: Enantioselective Total synthesis Conjugate addition Intermediate Copper-catalysed

Authors:

Takemoto, Yoshiji

Kuraoka, Satoru

Ohra, Taiichi

Yonetoku, Yasuhiro

Iwata, Chuzo

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Article abstract of DOI:10.1039/CC9960001655

By applying a new enantioselective Cu-catalysed conjugate addition of Me₃Al, (-)-solavetivone 1 is synthesized stereoselectively from cyclohexa-2,5-dienone 4, prepared from a chiral compound 6 using a regioselective Hg^II-mediated cyc

Full text of DOI:10.1039/CC9960001655

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