Tetrahedron p. 11793 - 11802 (1994)
Update date:2022-07-29
Topics:
Djuardi, Elsa
Bovonsombat, Pakorn
Mc Nelis, Edward
2-Haloethynyl-2-norbornanols react with iodine and Koser's reagent in acetonitrile to afford two ring-expanded products, 2-[(Z)-haloiodomethylidene]bicyclo[3.2.1]octan-3-one and 3-[(Z)-haloiodomethylidene]bicyclo[3.2.1]octan-2-one. These results contrast with the 2-haloethynyl-2-bornanols which lead to the corresponding 3-octanones.
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