Tetrahedron p. 14917 - 14928 (1996)
Update date:2022-08-05
Topics: Oxidation Regiochemistry Unsymmetrical Hydroxylamines n,n-disubstituted Mercury(II) oxide
Ali, Sk. Asrof
Hashmi, S. M. Azhar
Siddiqui, Mohammad N.
Wazeer, Mohammed I. M.
Mercury(II) oxide oxidation of N,N-disubstituted hydroxylamines with the α and α' carbon atoms containing one and two hydrogen atoms, respectively, gave aldonitrones in a highly regioselective manner. Removal of the α proton is involved in the rate determining step as shown by primary kinetic isotope effect.
View MoreSuzhou Chiral Pharmaceuticals Co., Ltd.
Contact:86-0512-63197058
Address:Building A, No. 2358, Chang'an Road, Wujiang Science Park
zhuzhou zhongle chemical co. ltd.
Contact:+86-0731 28228409
Address:Zhuzhou, Hunan, China
Xi'an caijing Opto-Electrical Science & Technology Co., LTD
Contact:+86-29-88294447
Address:NO.168 Zhangba Rd. East, Xi'an, P.R.China
Zhejiang Sucon Silicone Co.,Ltd
Contact:+86-575-88046692
Address:Qisheng Rd., Paojiang Industrial Zone, Shaoxing, Zhejiang, China.
Taizhou Chemedir Biopharm-tech Co., Ltd
Contact:+86 523 86200218
Address:G09, No. 1 Avenue China Medical City, Taizhou,Jiangsu, China
Doi:10.1021/jo961108t
(1996)Doi:10.1016/0040-4020(96)00849-6
(1996)Doi:10.1016/0040-4039(96)01963-6
(1996)Doi:10.1002/anie.200700632
(2007)Doi:10.1021/jo960393d
(1997)Doi:10.1007/BF01169234
(1996)