Tetrahedron p. 14917 - 14928 (1996)
Update date:2022-08-05
Topics: Oxidation Regiochemistry Unsymmetrical Hydroxylamines n,n-disubstituted
Ali, Sk. Asrof
Hashmi, S. M. Azhar
Siddiqui, Mohammad N.
Wazeer, Mohammed I. M.
Mercury(II) oxide oxidation of N,N-disubstituted hydroxylamines with the α and α' carbon atoms containing one and two hydrogen atoms, respectively, gave aldonitrones in a highly regioselective manner. Removal of the α proton is involved in the rate determining step as shown by primary kinetic isotope effect.
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