Highly Stereoselective Synthesis of cis-2-Substituted-3-vinyltetrahydrofurans from (Z)-Trimethyl(5-trimethylsiloxy-2-pentenyl)silane and Acetals

DOI: 10.1055/s-1997-3261

Source and publish data:

Synlett p. 716 - 718 (1997)

Update date:2022-08-03

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Authors:

Sano, Tomohumi

Oriyama, Takeshi

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Article abstract of DOI:10.1055/s-1997-3261

A variety of cis-2-substituted-3-vinyltetrahydrofurans are easily and stereoselectively produced by the reaction of acetals with (Z)-trimethyl(5-trimethylsiloxy-2-pentenyl)silane under the influence of a catalytic amount of trimethylsilyl trifluoromethanesulfonate under very mild conditions.

Full text of DOI:10.1055/s-1997-3261

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