Photoinduced reactions of phenyl-substituted acetonitriles in the presence of amine

DOI: 10.1248/cpb.45.1198

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1198 - 1201 (1997)

Update date:2022-08-03

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Authors:

Homma Homma

Yamada Yamada

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Article abstract of DOI:10.1248/cpb.45.1198

Irradiation of phenylacetonitrile and its derivatives (1) in the presence of triethylamine gave α-benzylated triethylamine (2), bibenzyl (3), and toluene (4) derivatives. The formation of these products was explained in terms of a benzylic radical intermediate formed by electron transfer between the substrate and triethylamine, followed by elimination of a cyanide anion from the radical anion of 1.

Full text of DOI:10.1248/cpb.45.1198

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