Synthesis and X-band EPR spectra of binary and ternary complexes of copper(II) with salicylideneanthranilic acid and imidazoles

Article abstract of DOI:10.1080/00945719708000253

The synthesis and EPR spectra of some binary and ternary complexes of copper(II) with a terdentate ligand, salicylideneanthranilic acid (H₂SAA) and some monodentate imidazoles viz. imidazole (im) and 2-ethylimidazole (e-im), are described. The binary complex with copper(II) and salicylideneanthranilic acid shows a subnormal magnetic moment and EPR spectra for spin-spin interaction. The zero-field splitting parameter D has been evaluated as 190 G and the copper-copper distance as 5.227 A. The ternary complexes show magnetic moments and EPR spectra which suggest a distorted tetrahedral geometry around copper(II).

Full text of DOI:10.1080/00945719708000253

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Synthesis and Reactivity in
Inorganic and Metal-Organic
Chemistry
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Synthesis and X-Band Epr
Spectra of Binary and Ternary
Complexes of Copper(II) with
Salicylideneanthranilic Acid
and Imidazoles
Ram N. Patel a & Krishna B. Pandeya a
a Departement of Chemistry , Awadhesh Pratap
Singh University , Rewa (M.P.), 486 003, India
Published online: 22 Aug 2006.
To cite this article: Ram N. Patel & Krishna B. Pandeya (1997) Synthesis
and X-Band Epr Spectra of Binary and Ternary Complexes of Copper(II) with
Salicylideneanthranilic Acid and Imidazoles, Synthesis and Reactivity in Inorganic and
Metal-Organic Chemistry, 27:8, 1149-1157, DOI: 10.1080/00945719708000253
To link to this article: http://dx.doi.org/10.1080/00945719708000253
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