Tetrahedron Letters p. 6845 - 6848 (1997)
Update date:2022-08-03
Topics:
Kato, Michiharu
Kosugi, Hiroshi
Kodaira, Ariko
Hagiwara, Hisahiro
Vogler, Bernhard
Stereocontrolled synthesis of (+)-trans-decalone 7 (R = CH=CH2) from (-)-verbenone (5), readily obtainable from (+)-nopinone (2), is described. The compound 7 possesses four correctly arranged chiral centers, C(5)-C(10)-C(9)-C(8), necessary for the enantioselective synthesis of neo-trans-clerodanes.
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Doi:10.1016/S0960-894X(97)10009-9
(1997)Doi:10.1021/jm9706426
(1998)Doi:10.1016/0040-4039(96)00764-2
(1996)Doi:10.1039/P19960001327
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(1996)Doi:10.1021/jm0491400
(2005)
