Stereocontrolled synthesis of the key intermediate for the enantioselective synthesis of clerodane natural products

DOI: 10.1016/S0040-4039(97)01614-6

Source and publish data:

Tetrahedron Letters p. 6845 - 6848 (1997)

Update date:2022-08-03

Topics:

Authors:

Kato, Michiharu

Kosugi, Hiroshi

Kodaira, Ariko

Hagiwara, Hisahiro

Vogler, Bernhard

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Article abstract of DOI:10.1016/S0040-4039(97)01614-6

Stereocontrolled synthesis of (+)-trans-decalone 7 (R = CH=CH₂) from (-)-verbenone (5), readily obtainable from (+)-nopinone (2), is described. The compound 7 possesses four correctly arranged chiral centers, C(5)-C(10)-C(9)-C(8), necessary for the enantioselective synthesis of neo-trans-clerodanes.

Full text of DOI:10.1016/S0040-4039(97)01614-6

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Product name:2-[(1R,2R,6R)-3-acetyloxy-1,2-dimethyl-6-(1-methylvinyl)cyclohex-3-enyl]ethyl acetate

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