Preparation of ortho-Aryl-benzaldehyde Derivatives via Free-Radical ipso-Substitution of an Amidomethyl Group

DOI: 10.1002/hlca.19970800714

Source and publish data:

Helvetica Chimica Acta p. 2148 - 2156 (1997)

Update date:2022-07-29

Topics:

Authors:

Giraud, Luc

Lacote, Emmanuel

Renaud, Philippe

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/hlca.19970800714

Preparation of 2-biarylcarbaldehydes using an intramolecular free-radical ipso-substitution is described. The two aryl moieties to be coupled are pre-associated using a glycolamide derivative. An unusual amidomethyl leaving group was successfully employed in this process.

Full text of DOI:10.1002/hlca.19970800714

Products guided by the article

Product name:2-(2-bromophenyl)-1,3-oxazolidin-4-one

Cas No:199939-07-6

R&D Labs maybe for 199939-07-6

Clearsynth Labs Limited

Contact:+91 - 22 - 26355700

Address:17, Lotus Business Park, Andheri West
Nanjing distinctions Medical Technology Co., Ltd.(expird)

Contact:+86-15996203785 13914714059

Address:nanjing,jiangsu , China
FUJIAN SHANSHUI CHEMICAL CORP.LTD.

Contact:+86-151-59920036

Address:Jinqiao Gareden, jo@fj-xinyi.com
Zhejiang Kente Chemical Co.,Ltd.

Contact:86-0576-87651912

Address:No.7, Fengxi West Road, Modern Industrial Zone
zhejiang huangyan wanfeng pharm chem co.ltd

Contact:+86-576- 84160728

Address:No. 5 Dazha Road, Economic,Development Zone(JiangKou), Zhejiang, China

Relevant to this article

Doi:10.1246/bcsj.38.858
(1965)
Analysis of an Active Deformylation Mechanism of 5-Formyl-deoxycytidine (fdC) in Stem Cells

Doi:10.1002/anie.202000414
(2020)
Convenient and efficient synthesis of novel 11: H -benzo[5,6][1,4]thiazino[3,4- a] isoindol-11-ones derived from 2-bromo-(2/3-substitutedphenyl)-1 H -indene-1,3(2 H)-diones

Doi:10.1039/c9ra02403d
(2019)
Transition metal complexes in organic synthesis, part 49. Development of novel chiral catalysts for the asymmetric catalytic complexation of prochiral cyclohexa-1,3-dienes by the tricarbonyliron fragment - Mechanism of the asymmetric catalysis and involvement of a dinuclear iron cluster

Doi:10.1055/s-1999-2626
(1999)
Nucleoside analog-based phosphonates via photochemical, single electron transfer (SET) induced rearrangements of allyl phosphites

Doi:10.1016/S0040-4039(97)10678-5
(1998)
Substituted 2-(R)-Methyl piperazines as muscarinic M₂ selective ligands

Doi:10.1016/S0960-894X(02)00023-9
(2002)

Article Doi