Bioorganic and Medicinal Chemistry Letters p. 113 - 116 (1998)
Update date:2022-09-26
Topics:
Takahashi, Takashi
Tsukamoto, Hirokazu
Yamada, Haruo
Glycosidation, using the methylthio derivative of N-acetylneuraminic acid 3, of linker alcohol 4 in DME with 'long-range participation' produced the α-glycosyl linkage with high stereoselectivity. The α-linked sialic acid 2 was introduced in taxol without protection of the alcohol functionality in sialic acid.
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