Tetrahedron Letters p. 1199 - 1202 (1998)
Update date:2022-08-03
Topics:
Ishii, Akihiro
Miyamoto, Fumie
Higashiyama, Kimio
Mikami, Koichi
The asymmetric synthesis of 1-substituted 1-phenyl-2,2,2-trifluoroethylamines from chiral 1,3-oxazolidines is described. The stereospecific substitution reaction with organolithium reagents of chiral 1,3-oxazolidines having a trifluoromethyl group proceeds with retention to control the newly created quaternary center.
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