Vinylidene complexes of osmium(0) derived from 1-naphthyl- or 2-naphthyl-carbyne complexes by hydride addition to the naphthyl substituents. The crystal structure of Os(=C=C10H8)(CO)2(PPh3)2

DOI: 10.1016/S0022-328X(98)00451-3

Source and publish data:

Journal of Organometallic Chemistry p. 153 - 158 (1998)

Update date:2022-08-03

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Authors:

Baker, Lisa-J.

Rickard, Clifton E.F.

Roper, Warren R.

Woodgate, Scott D.

Wright, L. James

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Article abstract of DOI:10.1016/S0022-328X(98)00451-3

When treated with lithium triethylborohydride, the cationic carbyne complexes [Os(-CR)(CO)₂(PPh₃)₂]⁺(R=1-naphthyl, 1; R=2-naphthyl, 2) form 3 and 4, respectively, which both have the formula Os(C₁₁H View More

Full text of DOI:10.1016/S0022-328X(98)00451-3

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