Hydrogen abstraction reactions of peroxydisulfuryl difluoride

Article abstract of DOI:10.1021/ic50130a028

Several new as well as a large number of known fluorosulfate-containing molecules have been synthesized via hydrogen radical abstraction with S₂O₆F₂. In general, the reactions were moderated sufficiently to permit wide applicability of this synthetic approach by dilution of the reactants and by lowering of the temperature. Amine, alcohol, aromatic, aliphatic, perfluoroalkyl, hydrogen halide, and thiol hydrogens were easily abstracted and in most cases converted to stable fluorosulfate products.