7,8-Benzo-11-chlorometacyclophane

DOI: 10.1039/c39800000424

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 424 - 425 (1980)

Update date:2022-08-03

Topics:

Authors:

Grice, Peter

Reese, Colin B.

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Article abstract of DOI:10.1039/c39800000424

The <5>metacyclophane derivative (3) was obtained in 55percent isolated yield by treatment of (2) with silver perchlorate in the presence of 2,6-lutidine in tetrahydrofuran solution; (3) isomerizes to (6) in acidic solution and is converted by hydrogen bromide in benzene-acetic acid-water into a mixture consisting mainly of (6), (8a), and (8b).

Full text of DOI:10.1039/c39800000424

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