Russian Chemical Bulletin p. 934 - 937 (1999)
Update date:2022-08-04
Topics:
Glushakova
Skorodumova
Nevodchikov
Abakumova
Makarenko
Cherkasov
Druzhkov
Reaction of 3,6-di-tert-butyl-1,2-benzoquinone and 3,6-di-tert-butylcatechol with tert-butyl hydroperoxide in aprotlc solvents leads to the generation of semiquinone (SQ 'H), alkylperoxy (ROO'), and alkyloxy radicals. The reaction of SQ'H and ROO' produces 2,5-di-tert-butyl-6-hydroxy-1,4-benzoquinone, 3,6-di-tert-butyl-1-oxacyclohepta-3,5-diene2,7-dione, and 2,5-di-tert-butyl-3,6-dihydroxy-1,4-benzoquinone. The radical generated from solvent attacks SQ' H at position 4 with C-C bond formation. 4-Benzyl-2,5-di-tert-butyl-6-hydroxycyclohexa-2,5-diene-1-dione produced in this way is transformed into 4-benzyl-3,6-di-tert-butyl-1,2-benzoquinone under the reaction conditions.
View MoreShangyu Sanhechemicals Co.,LTD.
Contact:86-0571-56696839
Address:Num.2952,Nanhuan Road,Binjiang District,Hangzhou,China
Contact:(86) 731 88718666
Address:Room 1222, Unit 4, Building B, Shangcheng, No.47, Kaiyuan East Road.
FUJIAN SHANSHUI CHEMICAL CORP.LTD.
Contact:+86-151-59920036
Address:Jinqiao Gareden, jo@fj-xinyi.com
Contact:0086-27-83607103/83642615
Address:No.498, Jianshe Ave, Wuhan, China
Contact:+44 (0)161 367 9441
Address:
Doi:10.1002/adsc.200606222
(2006)Doi:10.1021/jo981906e
(1999)Doi:10.1021/ol990813w
(1999)Doi:10.1021/jm00304a026
(1969)Doi:10.1134/S107036321204010X
(2012)Doi:10.1021/acs.joc.6b01707
(2016)