Synthesis and characterization of novel octahedral cobalt(III) complexes

Article abstract of DOI:10.1080/00945719909351731

The novel octahedral cobalt(III) complexes [Co(HL)BrL′]ClO₄ have been prepared by the reaction of (E,E)-3,9-dimethyl-5,7-di-oxa-4,8-diaza-3,8-undecadiene-2,10-dione dioxime (H₂L) and CoBr₂.6H₂O. The complexes of H₂L have a metal : ligand ratio of 1:1 and the ligand coordinates through the N atoms, as in most oximes, with axial ligation by substitued pyridines (L′) and bromide ion. The cobalt complexes have been characterized by ¹H NMR, IR, MS spectral and elemental analysis data.

Full text of DOI:10.1080/00945719909351731

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Synthesis and Reactivity in
Inorganic and Metal-Organic
Chemistry
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Synthesis and Characterization
of Novel Octahedral Cobalt(Iii)
Complexes
Nevin Karaböcek a & Yaşar Gök a
a Department of Chemistry , Karadeniz Technical
University , 61080, Trabzon, Turkey
Published online: 23 Apr 2008.
To cite this article: Nevin Karaböcek & Yaşar Gök (1999) Synthesis and
Characterization of Novel Octahedral Cobalt(Iii) Complexes, Synthesis and
Reactivity in Inorganic and Metal-Organic Chemistry, 29:10, 1723-1731, DOI:
10.1080/00945719909351731
To link to this article: http://dx.doi.org/10.1080/00945719909351731
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