ENANTIOSELECTIVE DEHYDROHALOGENATION VIA ASYMMETRIC DEPROTONATION BY CHIRAL LITHIUM AMIDES: DERACEMIZATION OF A COMPOUND BEARING A CHIRAL AXIS

DOI: 10.1016/S0040-4039(00)96768-6

Source and publish data:

Tetrahedron Letters p. 5517 - 5520 (1987)

Update date:2022-08-03

Topics:

Authors:

Duhamel, Lucette

Ravard, Alain

Plaquevent, Jean-Christophe

Davoust, Daniel

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Article abstract of DOI:10.1016/S0040-4039(00)96768-6

Chiral lithium amides exert asymmetric induction in dehydrohalogenation reactions leading to axially dissymmetric compounds.Thus the deracemization of 4-tert-butyl-cyclohexylidene acetic acid 1 via the prochiral hydrochlorinated intermediate 2 is reported

Full text of DOI:10.1016/S0040-4039(00)96768-6

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