Tetrahedron Letters p. 2343 - 2346 (1993)
Update date:2022-08-03
Topics:
Lee, Eun
Lee, Chulbom
Tae, Jin Sung
Whang, Ho Sung
Li, Kap Sok
Bromopropyl aryl ethers an converted to 3-arylpropanols under standard radical generating conditions in the presence of tributylstannane and AIBN. This rearrangement involves intramolecular ipso attack of the alkyl radicals which generates spiro cyclohexadienyl radical intermediates.
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Doi:10.1016/j.jorganchem.2018.02.028
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