Journal of the Chemical Society. Perkin transactions I p. 1869 - 1874 (1984)
Update date:2022-08-04
Topics:
Katada, Tomonori
Eguchi, Shoji
Esaki, Toshiyuki
Sasaki, Tadashi
The thermal cycloaddition reaction of adamantanethione (1) with α,β-unsaturated carbonyl compounds such as acrolein, methacrolein, and methyl vinyl ketone occurred smoothly at 80 - 140 deg C to afford, regioselectively, adamantane-2-spiro-2'-(1'-oxa-3'-thiacyclohex-5'-enes) (3a-e) as novel <4 + 2> cycloadducts in good yield.The nature of this cycloaddition is discussed on the basis of kinetics, solvent effects, and FMO theory.
View MoreHangzhou Hysen Pharma co.,Ltd.
website:http://www.hysenpharma.cn/
Contact:0086-571-88298791
Address:#701,Gudun Road Hangzhou
WENZHOU M&C FOREIGN TRADE CO.,LTD.
Contact:+86-577-88862917
Address:No.8 Liming West Road,Wenzhou,zhejiang,China
Beijing Stable Chemcial Co.ltd
Contact:86-10-63785052
Address:A1301 Technological Edifice. No.4 FuFeng Road,FengTai District, Beijing. China
SHAANXI TOP PHARM CHEMICAL CO.LTD
Contact:+86-029-85733403
Address:No.108 ,west sector,south er huan,xi'an,china
Zhengzhou Institute of Chiral Pharmer Research Co., Ltd.
Contact:86-371-55219111
Address:15 Floor, 2 Building, Central China Technovalley, Zhongyuan West Road
Doi:10.1002/oms.1210031210
(1970)Doi:10.1248/cpb.48.1549
(2000)Doi:10.1016/0040-4039(94)02264-C
(1995)Doi:10.1021/ic000268r
(2000)Doi:10.1016/S0223-5234(99)80018-X
(1998)Doi:10.1016/S0040-4020(02)00571-9
(2002)
