A radical mechanism of the reaction of molybdenum carbonyl complexes with bis(triethylgermyl)mercury

DOI: 10.1007/BF00699201

Source and publish data:

Russian Chemical Bulletin p. 1585 - 1587 (1993)

Update date:2022-09-26

Topics:

Authors:

Sykhrannova, M. I.

Tatarnikov, A. N.

Khorshev, S. Ya.

Gladyshev, E. N.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1007/BF00699201

The reaction of 2 with (Et3Ge)2Hg occurs in toluene and THF by a radical mechanism.The interaction between 2Hg and (Et3Ge)2Hg has a radical character only in THF.The formation of Cp(CO)3MoH at the first stage of these reactions substantially affects the further course of the process.

Full text of DOI:10.1007/BF00699201

Products guided by the article

Product name:(C₅H₅)Mo(CO)3Ge(C₂H₅)3

Cas No:33519-67-4

R&D Labs maybe for 33519-67-4

Tianjin Realet Chemical Technology Co.,Ltd.

website:http://www.realetchem.com

Contact:+86-022-58788819

Address:shuanggang industrial park
Xiamen Hisunny Chemical Co.,Ltd

website:http://www.hisunnychem.com

Contact:+86-592-3327115

Address:Unit 603,No.879,Xiahe Road,Meixin Building,Xiamen,China
Nanjing Chemipioneer Pharma&Tech Co.,Ltd

website:http://www.chemipioneer.com.cn

Contact:+86-25-52685700

Address:Room 305，A Block，Biological-Medicine Building，Business Start-up Center，Xin-ke 1st Road, High-tech development zone，Nanjing city，Jiangsu Province, China
PharmOrgsyn

Contact:+86-21-38228826

Address:Room 505 Building 2, No 3377 Kangxin Highway, Shanghai, Republic China
Lianyungang Ningkang Chemical Co., Ltd

Contact:.+86-518-88588008

Address:http://www.chemnk.com

Relevant to this article

Short synthesis of 5-substituted-2,3,4,5-Tetrahydro-Benzo[f][1,4] Thiazepines by using a modified pictet-spengler reaction

Doi:10.3987/COM-17-13705
(2017)
Ester derived titanium enolate aldol reaction: Chelation controlled diastereoselective synthesis of syn-aldols

Doi:10.1016/S0040-4039(00)02227-9
(2001)
Saturated heterocycle-condensed diphenylisoindolones: Fused-skeleton tetrahydro-1,3-oxazines, oxazolidines and imidazolidines

Doi:10.1016/0022-2860(96)09311-8
(1996)
Catalytic amidation of unactivated ester derivatives mediated by trifluoroethanol

Doi:10.1039/c5cc02895g
(2015)
β-scission of tertiary alkyl hypochlorites promoted by phase-transfer catalysis

Doi:10.1021/jo9911847
(2000)
Practical entry into the HIJKLM ring segment of ciguatoxin CTX3C

Doi:10.1039/b009506k
(2001)

Article Doi