A radical mechanism of the reaction of molybdenum carbonyl complexes with bis(triethylgermyl)mercury

DOI: 10.1007/BF00699201

Source and publish data:

Russian Chemical Bulletin p. 1585 - 1587 (1993)

Update date:2022-09-26

Topics:

Authors:

Sykhrannova, M. I.

Tatarnikov, A. N.

Khorshev, S. Ya.

Gladyshev, E. N.

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Article abstract of DOI:10.1007/BF00699201

The reaction of 2 with (Et3Ge)2Hg occurs in toluene and THF by a radical mechanism.The interaction between 2Hg and (Et3Ge)2Hg has a radical character only in THF.The formation of Cp(CO)3MoH at the first stage of these reactions substantially affects the further course of the process.

Full text of DOI:10.1007/BF00699201

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