Monoalkylation of Primary Aliphatic Amines via N-Alkyl-N-(alkylthiomethyl)ammonium Chlorides. Evidence for the Formation of Stable N-Methylenealkylamines

DOI: 10.1039/c39840000427

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 427 - 428 (1984)

Update date:2022-07-30

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Authors:

Barluenga, Jose

Bayon, Ana M.

Asensio, Gregorio

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Article abstract of DOI:10.1039/c39840000427

Monomeric N-methylenealkylamines (3), formed from N-alkyl-N-(alkylthiomethyl)ammonium chlorides (5) are stable at -60 deg C and may be trapped with organometallic reagents to provide the N,N-dialkylamines (8).

Full text of DOI:10.1039/c39840000427

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