Tetrahedron Letters p. 3649 - 3651 (2001)
Update date:2022-09-26
Topics:
Kadota, Isao
Takamura, Hiroyoshi
Yamamoto, Yoshinori
The J ring segment 2 of gambieric acid was synthesized stereoselectively by the coupling between the cyclic ether component 3 and the alkenyl iodide 4. The tetrahydropyran 3 was stereoselectively synthesized by the 6-endo-cyclization of a hydroxyepoxide prepared from deoxy-D-ribose. The side chain moiety 4 was prepared by the stereoselective hydrostannation of an internal alkyne.
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(2001)Doi:10.1016/j.tetlet.2007.10.076
(2007)Doi:10.1081/NCN-100002082
(2001)
