NEW C-N-C BOND FORMATION REACTION USING NITROGENATION-TRANSMETALLATION PROCESS. NOVEL RING CONSTRUCTION OF INDOLE AND QUINOLINE DERIVATIVES.

DOI: 10.3987/COM-91-S88

Source and publish data:

Heterocycles p. 819 - 830 (1992)

Update date:2022-08-02

Topics:

Authors:

Mori, Miwako

Uozumi, Yasuhiro

Shibasaki, Masakatsu

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Article abstract of DOI:10.3987/COM-91-S88

Ketones and aryl or vinyl halides couple to give divinyl- or arylvinylamines in the presence of the titaniumisocyanate complex <3THF*Mg2Cl2O*TiNCO> (1) and a palladium catalyst, via transmetallation of the titano imine complex (3) with aryl- or vinylpalladium bromide.

Full text of DOI:10.3987/COM-91-S88

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