Journal of Carbohydrate Chemistry p. 73 - 84 (2005)
Update date:2022-08-03
Topics:
Suzuki, Katsuhiko
Suzuki, Nobuyuki
Yamaura, Masanori
Yoshizawa, Toyokichi
The first synthesis of 3-O-β-D-glucopyranosyl-(3R)-hydroxybutanolide (Kinsenoside) and 3-O-β-D-glucopyranosyl-(3S)-hydroxybutanolide (Goodyeroside A) is described. The diastereomers of the aglycon in 2-O-β-D-gulucopyranosyl-1,2,4-butanetriol derivatives, which were separable precursors of Kinsenoside and Goodyeroside A, were synthesized from optically nonactive 1,2,4-butanetriol and α-D-glucopyranosyl trichloroacetimidate in excellent yields. Copyright Taylor & Francis, Inc.
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