Stereospecificity in the Rearrangement Reactions of an N-Phosphinoyl-O-sulfonylhydroxylamine with Methylamine and tert-Butylamine: Retention of Configuration at Phosphorus as Evidence for the Initial Formation of a Phosphonamidic Sulfonic Mixed Anhydride

DOI: 10.1039/P19940003261

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 3261 - 3268 (1994)

Update date:2022-08-03

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Authors:

Harger, Martin J. P.

Sreedharan-Menon, Ramesh

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Article abstract of DOI:10.1039/P19940003261

Reaction of the N-phosphinoyl-O-sulfonylhydroxylamine PhMeCH(Ph)P(O)NHOMs 10 with RNH2 (R = Me or t-Bu) results in migration of the phenyl group from phosphorus to nitrogen which leads to the rearrangement product PhMeCHP(O)(NHPh)NHR.Using samples of 10 e

Full text of DOI:10.1039/P19940003261

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