Chemistry Letters p. 1497 - 1500 (1992)
Update date:2022-08-04
Topics:
Fukuzumi, Shunichi
Tokuda, Yoshihiro
Stable radical anions such as p-chloranil radical anion (Cl4Q-.) are reduced by NADH analogues, 1-benzyl-1,4-dihydronicotinamide (BNAH) and 10-methyl-9,10-dihydroacridine (AcrH2), to yield the corresponding hydroquinone anions.The addition of NaClO4 to the BNAH-Cl4Q-. system results in a significant increase in the rate of the one-electron reduction of Cl4Q-., while no acceleration effect has been observed by the addition of Bu4NClO4.
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