
Tetrahedron p. 2797 - 2799 (1974)
Update date:2022-08-04
Topics:
Breijer
Buurmans
Van De Graaf
Schuijl
Kieboom
The mass spectra of deuterium and 18O labeled 3-(m-nitrobenzoyl)-2-methylpropanoic acid reveal that the McLafferty rearrangement and the rearrangement process leading to protonated m-nitrobenzoic acid do not take place via a common intermediate. H-D exchange phenomena point to a stepwise McLafferty rearrangement.
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Doi:10.1021/jo010929h
(2002)Doi:10.1039/c5ob02336j
(2016)Doi:10.1016/S0008-6215(00)83067-0
(1974)Doi:10.1063/1.441661
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(2003)