Journal of Organometallic Chemistry p. C39 - C41 (1983)
Update date:2022-08-05
Topics:
Choi, Henry W.
Sollberger, Mark S.
?-(2,6-Dimethylpyridine)(triphenylphosphine)dicarbonylchromium was prepared by the photochemical reaction of ?-(2,6-dimethylpyridine)tricarbonylchromium with triphenylphosphine.Analogously, ?-(2,4,6-trimethylpyridine)(triphenylphosphine)dicarbonylchromium, ?-(2,6-dimethylpyridine)(trimethylphosphite)dicarbonylchromium, and ?-(2,6-dimethylpyridine)bis(trimethylphosphite)carbonylchromium were prepared.The phosphorus ligand substituted complexes were thermally more robust than their tricarbonyl analogs and showed a drastic inhibition toward arene exchange reactions.
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(1983)
