Synthesis and nucleophilic substitution of allenyl(m-nitrophenyl)iodanes as a new propynyl cation-equivalent species: Synthesis of propynyl ethers, esters, and amides

DOI: 10.1039/cc9960001933

Source and publish data:

Chemical Communications p. 1933 - 1934 (1996)

Update date:2022-09-26

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Authors:

Kida, Michio

Sueda, Takuya

Goto, Satoru

Okuyama, Tadashi

Ochiai, Masahito

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Article abstract of DOI:10.1039/cc9960001933

Treatment of diacetoxy(m-nitrophenyl)iodane with propynylsilanes in the presence of BF₃·Et₂O gives allenyl(m-nitrophenyl)iodanes, which act as propynyl cation-equivalent species and undergo regioselective nucleophilic substitution wi

Full text of DOI:10.1039/cc9960001933

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