A New Route to the Pavine (5,6,11,12-Tetrahydro-5,11-imino-13-methyl-dibenzocyclo-octene) Skeleton: Synthesis of (+/-)-Argemonine

DOI: 10.1039/c39820001113

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1113 - 1115 (1982)

Update date:2022-08-05

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Authors:

Nomoto, Takashi

Takayama, Hiroaki

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Article abstract of DOI:10.1039/c39820001113

A new route to the pavine skeleton was investigated starting from the readily accessible tetrahydro-6,12-methanodibenzazocine (1, R = H or Me); an efficient synthesis of a typical pavine alkaloid (+/-)-argemonine (6, R = OMe) from (1, R = OMe) was accomplished in 53percent overall yield.

Full text of DOI:10.1039/c39820001113

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