Bulletin of the Chemical Society of Japan p. 953 - 954 (1983)
Update date:2022-07-30
Topics:
Ogura, Katsuyuki
Aizawa, Teruki
Uchiyama, Koichiro
Iida, Hirotada
The PdCl2 complexes coordinated with methyl p-tolyl sulfoxide (1:2), methylthiomethyl p-tolyl sulfoxide (1:2), and 1,3-bis<(p-tolylsulfinyl)methylthio>propane (1:1) as ligands were prepared.Among these complexes, bis(methyl p-tolyl sulfoxide)palladium dichloride catalyzed effectively cyclotrimerization of diphenylethyne and rearrangement of 3-acetoxy-1-tridecene to 1-acetoxy-2-tridecene.
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Doi:10.1021/jo00152a022
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