Stereoselective dimerization of α-keto amides using samarium diiodide

DOI: 10.1016/0040-4039(96)01769-8

Source and publish data:

Tetrahedron Letters p. 7755 - 7756 (1996)

Update date:2022-07-29

Topics:

Authors:

Yamashita, Masayuki

Okuyama, Kazunori

Kawasaki, Ikuo

Ohta, Shunsaku

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Article abstract of DOI:10.1016/0040-4039(96)01769-8

α-Keto amides were dimerized in the presence of SmI₂ in THF to give substituted tartaric amides in moderate to good yields. Although the dimerization of the secondary keto amides did not proceed stereoselectively, racemic tartaric amides were p

Full text of DOI:10.1016/0040-4039(96)01769-8

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