Journal of the American Chemical Society p. 1954 - 1960 (1980)
Update date:2022-07-30
Topics:
Confalone, Pat N.
Pizzolato, Giacomo
Confalone, Dianne Lollar
Uskokovic Milan R.
A novel synthesis of biotine (6) from cycloheptene (4) via the key amino alcohol 5 is described.The synthetic scheme is based upon an intramolecular nitrone-olefin <3 + 2> cycloaddition of the reactive intermediate 13, generated in situ from the aldehyde
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Doi:10.1021/ol0269289
(2002)Doi:10.1039/c4cc09987g
(2015)Doi:10.1007/s10593-012-1073-4
(2012)Doi:10.1021/ja00529a031
(1980)Doi:10.1016/S0040-4039(00)71427-4
(1980)Doi:10.1021/acscatal.7b01523
(2017)
