Journal of the American Chemical Society p. 1954 - 1960 (1980)
Update date:2022-07-30
Topics:
Confalone, Pat N.
Pizzolato, Giacomo
Confalone, Dianne Lollar
Uskokovic Milan R.
A novel synthesis of biotine (6) from cycloheptene (4) via the key amino alcohol 5 is described.The synthetic scheme is based upon an intramolecular nitrone-olefin <3 + 2> cycloaddition of the reactive intermediate 13, generated in situ from the aldehyde
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Doi:10.1021/ol0269289
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