CHIRAL HOMOENOLATE EQUIVALENTS. I. ASYMMETRIC SYNTHESIS OF β-SUBSTITUTED ALDEHIDES VIA METALATED CHIRAL ALLYLAMINES

DOI: 10.1016/S0040-4039(00)77438-7

Source and publish data:

Tetrahedron Letters p. 3175 - 3178 (1980)

Update date:2022-08-04

Topics:

Authors:

Ahlbrecht, Hubertus

Bonnet, Gerhard

Enders, Dieter

Zimmermann, Gerd

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)77438-7

Metalated chiral allylamines of type 2 (M = Li, K) are used as chiral homoenolate equivalents and allow after alkylation and acidic hydrolysis asymmetric C-C bond formations to β-substituted aldehydes in enantiomeric excesses up to 67percent.

Full text of DOI:10.1016/S0040-4039(00)77438-7

Products guided by the article

Product name:3-Phenylheptyl-acetat

Cas No:75834-23-0

R&D Labs maybe for 75834-23-0

Jiangsu Willing Bio-Tech Co ltd

website:http://www.willingbio.com/

Contact:+86 18796908173

Address:No 18 Guoqiao Road
Shanghai united Scientific Co.,Ltd.

Contact:+86-21-53535353

Address:28F No.900 huaihai Road Shanghai China
XI'AN CHUKANG BIOTECHNOLOGY CO.,LTD

Contact:29-63685658 63685359

Address:Room 3-1202,Building 1,Oriental oasis,East of Xianning Road,Xi'an,Shaanxi 710043 P.R.China
Shanghai Forever Synthesis Co.,Ltd.

Contact:021-61124658

Address:Zhoukang Road,Pudong New District,Shanghai,China
Zibo Xiaoguang Chemical Material Co., Ltd

Contact:15954099116

Address:Boshan Development Zone

Relevant to this article

Detection of a single DNA base-pair mismatch using an anthracene-tagged fluorescent probe

Doi:10.1039/b611650g
(2006)
Doi:10.1007/BF00904443
(1962)
Synthesis, reactions, and antiviral activity of 1-(1H-pyrazolo[3,4-b] pyridin-5-yl)ethanone and pyrido[2′,3′:3,4]pyrazolo[5,1-c][1,2,4] triazine derivatives

Doi:10.1080/10426500500326404
(2006)
Palladium nanoparticles supported on polyaniline nanofibers as a semi-heterogeneous catalyst in water

Doi:10.1002/anie.200701389
(2007)
ONE ELECTRON OXIDATION OF BENZYL AND 2-PHENYLETHYL PHENYL ETHERS. THE FATE OF THE INTERMEDIATE RADICAL CATIONS

Doi:10.1016/S0040-4020(01)89173-0
(1989)
A DEHYDROALANINE ROUTE TO AN ACTIVATED PHENOLIC SPARSOMYCIN ANALOG

Doi:10.1016/S0040-4039(01)81255-7
(1984)

Article Doi