CHIRAL HOMOENOLATE EQUIVALENTS. I. ASYMMETRIC SYNTHESIS OF β-SUBSTITUTED ALDEHIDES VIA METALATED CHIRAL ALLYLAMINES

DOI: 10.1016/S0040-4039(00)77438-7

Source and publish data:

Tetrahedron Letters p. 3175 - 3178 (1980)

Update date:2022-08-04

Topics:

Authors:

Ahlbrecht, Hubertus

Bonnet, Gerhard

Enders, Dieter

Zimmermann, Gerd

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Article abstract of DOI:10.1016/S0040-4039(00)77438-7

Metalated chiral allylamines of type 2 (M = Li, K) are used as chiral homoenolate equivalents and allow after alkylation and acidic hydrolysis asymmetric C-C bond formations to β-substituted aldehydes in enantiomeric excesses up to 67percent.

Full text of DOI:10.1016/S0040-4039(00)77438-7

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