Tetrahedron Letters p. 3175 - 3178 (1980)
Update date:2022-08-04
Topics:
Ahlbrecht, Hubertus
Bonnet, Gerhard
Enders, Dieter
Zimmermann, Gerd
Metalated chiral allylamines of type 2 (M = Li, K) are used as chiral homoenolate equivalents and allow after alkylation and acidic hydrolysis asymmetric C-C bond formations to β-substituted aldehydes in enantiomeric excesses up to 67percent.
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