Tetrahedron Letters p. 2993 - 2996 (1986)
Update date:2022-08-04
Topics:
Nuzillard, J. M.
Poulin, J. C.
Kagan, H. B.
(S,S)-Z-(O)Ts-Tyr-Gly2-ΔPhe-Leu-OMe was synthesized.Some chiral rhodium complexes catalyze the reduction of the C=C bond.The stereochemistry of reduction of the ΔPhe moiety was investigated. 93 percent de could be achieved with dipamp as ligand in the cat
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