Organometallic Complexes in Organic Synthesis. 15. Absolute Configurations of Some Simply Substituted Tricarbonyliron Complexes

Article abstract of DOI:10.1021/jo00338a021

Unsymmetrically substituted tricarbonyl(η-cyclohexadiene)iron(0) complexes have a molecular center of chirality.Stereospecific reactions of the derived tricarbonyl(η-cyclohexadienyl)iron(1+) salts have been used to direct the formation of new chiral cente